Put a thin spacer between two semiconducting monolayers, and the Stark effect gets much stronger.
- Stabiliser. The spacer holds the two atomically thin films apart and keeps the interface stable.
- Decoupler. It drives the bilayer towards a degenerate, monolayer-like electronic structure.
- Less screening. An out-of-plane field now shifts the two layers' bands against each other.
General rule: a Type-I (straddling) alignment. The spacer's VBM and CBM must enclose those of the active film; here MoS2 / hBN / MoS2.